python pandas resample dataframe lines to column group-pivot

from collections import OrderedDict
import pandas as pd

table = OrderedDict(( \
    ("MA",   ['11', '22', '33', '11', '22', '33']), \
    ('TY',['IN', 'IN', 'IN', 'OUT', 'OUT', 'OUT']), \
    ('TS',   ['00:00:11', '00:00:22', '00:00:33', '00:00:45', '00:00:46', '00:00:47'])))

d = pd.DataFrame(table)
print '\n'*3, d

pv = d.pivot(index='MA', columns='TY', values='TS')
print '\n'*3, pv