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- \documentclass{scrartcl}
- \usepackage{pgfplots}
- \usepackage{rotating}
- \usepackage{geometry}
- \renewcommand{\thesection}{\Roman{section}}
- \begin{document}
- \title{Compte-rendu de travaux pratiques de chimie}
- \subtitle{Spectrophotométrie}
- \author{Benjamin Loison (MPSI 1)}
- \date{16 février 2019}
- \maketitle
- \setcounter{section}{1}
- \section{Partie expérimentale}
- \subsection{Vérification de la loi de Beer-Lambert}
- \begin{tabular}{|c|c|}
- \hline La concentration $C$ (en mol/L) & L'absorbance $A$\\
- \hline 0.4 & 2.600 \\
- \hline 0.2 & 1.317 \\
- \hline 0.1 & 0.657 \\
- \hline 0.05 & 0.326 \\
- \hline 0.025 & 0.161 \\
- \hline 0.0125 & 0.090 \\
- \hline
- \end{tabular}\\\\
- \begin{tikzpicture}
- \begin{axis}[
- xlabel=$C$ (en mol/L),
- ylabel=$A$]
- \addplot[color = red, mark = x] coordinates {
- (0.4, 2.600)
- (0.2, 1.317)
- (0.1, 0.657)
- (0.05, 0.326)
- (0.025, 0.161)
- (0.0125, 0.090)
- };
- \end{axis}
- \end{tikzpicture}
- On remarque que en linéarisant l'ensemble de points du graphique, cela forme une portion de droite passant par l'origine, donc la loi de Beer-Lambert est vérfiée à partir des solutions étalons diluées.
- \subsection{Spectre d'un indicateur coloré acido-basique}
- Le graphique réalisé est disponible en annexe, en page \pageref{Annexe1}.\\
- Les spectres $A_b$ = f($\lambda$), $A_a$ = f($\lambda$) et $A$ = f($\lambda$) sont respectivement coloriés en rouge, vert et bleu.\\
- Le pH relevé pour la solution intermédiaire est 5,4.
- \subsubsection{Longueurs d'onde des maxima d'absorption}
- Les longueurs d'onde des maxima d'absorption du bleu de bromophénol pour les pH 9, 2 et 5,4 sont respectivement: 438 nm, 593 nm et 592 nm.
- Pour chacune des solutions on observe respectivement une couleur vert, bleu et bleu. Ce qui est en accord avec la couleur opposée sur le cercle chromatique à la couleur associée à la longueur d'onde d'absorption maximale. %fake visual
- \subsubsection{Point isobestique}
- \clearpage
- \afterpage{
- \newgeometry{left=1cm, right=1cm, top=1cm, bottom=2cm}
- \title{\vspace{-1cm}Annexe}
- \subtitle{} \author{} \date{}
- \maketitle
- \label{Annexe1}
- \begin{turn}{270}
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- \end{axis}
- \end{tikzpicture}
- \end{turn}
- \clearpage
- \restoregeometry
- }
- \end{document}
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